Thursday, January 12, 2012

The Features of carboxylated carbon nanotubes

carboxylated carbon nanotubes
Carboxylated carbon nanotubes acid rate (Carboxyl ratio) : 2.31 wt % (The rate of surface carbon atom: 8-14 mol %) water-soluble carbon nanotubes performance: but even immiscible in inorganic powder materials.
USES: preparing inorganic conductive or inorganic reinforced materials. Preparation of polymer conductive or polymer reinforced composites. Oil-soluble carbon nanotubes: performance: but even immiscible in polymer materials. CAS number: 308068-56-
Packing: bottled validity: a month
Carboxylated semiconductor and metallic carbon nanotubes under transverse electrical fields are investigated through density functional theory based on first-principles calculations. The external field polarizes the system, resulting in an induced electric dipole moment toward the incident field with the modulus directly dependent on the field strength. The structural and electronic properties of the resulting system due to the orbital hybridization between the nanotube and COOH states are shown to be affected by the applied field. These results open new perspectives for different potential uses, such as to enhance the capacity of the composite to bind and characterize other substances, especially polar molecules, and as mechanisms to monitor the bound substances or control electron injection or detection, by varying the external field through a controlled application.
To enhance its pseudocapacitance, ruthenium oxide must be formed with a hydrated amorphous and porous structure and a small size, because this structure provides a large surface area and forms conduction paths for protons to easily access even the inner part of the RuO2. In this study, we report that highly dispersed RuO2 nanoparticles could be obtained on carboxylated carbon nanotubes. This could be achieved by preventing agglomeration among RuO2 nanoparticles by bond formation between the RuO2 and the surface carboxyl groups of the carbon nanotubes. Highly dispersed RuO2 nanoparticles on carbon nanotubes showed an increased capacitance, which can be explained by the fact that with the decrease in size protons were able to access the inner part of RuO2, so that its utilization was increased. The high dispersion of RuO2 is therefore a key factor to increase the capacitance of nanocomposite electrode materials for supercapacitors.


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