Wednesday, February 29, 2012

Description of Metal ceramic MIM coated with iron nickel ceramic powder


Iron nickel coating graphite conductive filler is made from the heated graphite decompositing Fe(CO)5 and Ni(CO)4 . A high rate of coating, coating is adjustable , high conductivity, overcome the same products in abroad  up to 70% the amount of coating and the coating rate is still low, and the price is far lower than the same products abroad.

Tuesday, February 28, 2012

What is Graphite plating iron and nickel

Graphite is proved to be the most thin, the hardest substance in the world. Based on its chemical structure, graphite has many unique chemical and physical properties, such as high surface area, high conductivity, high mechanical strength, easy to modify and large scale production, etc.

Monday, February 20, 2012

Iron oxide nanoparticles Applications in. Biomedical,



Magnetite and maghemite are preferred in biomedicine because they are biocompatible and potentially non-toxic to humans. Iron oxide nanoparticles is easily degradable and therefore useful for in vivo applications. Results from exposure of a human mesothelium cell line and a murine fibroblast cell line to seven industrially important nanoparticles showed a nanoparticle specific cytotoxic mechanism for uncoated Iron oxide nanoparticles.Solubility was found to strongly influence the cytotoxic response
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Thursday, February 16, 2012

An overview of the Fe 3 (CO) 12


Fe 3 (CO) 12 is a black solid. The molecule, three iron atoms through the Fe-Fe bond combination is clusters of coordination compounds, containing two bridging carbonyl. The relative density of ° C). The melting point of 140 ° C (decomposition). Long-term exposure to oxidized into ferric oxide in the air. Fe 3 (CO) 12 does not dissolve in water, slightly soluble in benzene, ether, petroleum ether, acetone, the solution was dark green, soluble in the carbonyl iron, nickel carbonyl. Sodium metal reduction Na2Fe (CO) 4. Can be used in organic synthesis, catalysts, pharmaceuticals, infrared devices, 1.996 (18). Fe 3 (CO) 12 is usually the water is slightly harmful, not undiluted or a lot of product to reach ground water, water course or sewage system, without the permission of the government not to allow material to be discharged into the surrounding environment
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Tuesday, February 14, 2012

W (CO) 6 reaction

Tungsten hexachloride with pentacarbonyl iron role, generated hexacarbonyl tungsten. Fe (CO) □ carbon monoxide can occur with many ligand substitution reactions. Generation of mixed-ligand complexes of Fe (CO) L, □ □, where L is the PR □, □ AsR olefin or sulfur atom, etc. (R is alkyl). Yellow oily liquid; -21 ° C melting point, boiling point 102.8 ° C, the liquid density of 1.457 g / cm □ (21 ° C); 250 ° C decomposition of pure iron; insoluble in water, soluble in alkali, sulfuric acid, alcohol, benzene and petroleum ether . □ subjected to sunlight or ultraviolet irradiation of Fe (CO) dimerization to generate the Fe □ (CO) and carbon monoxide. Five carbonyl iron ether solution with mineral acid, decomposition into carbon monoxide, hydrogen, and ferrous iron. Strong base in aqueous or alcohol solution can be of Fe (CO) □ conversion into [HFe (CO) □] - anion
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Monday, February 6, 2012

The Advantages of Rink Resin

Rink Resin
Rink resin is a battery-acid adaptable rosin wide used to educate amides , amide differentials, and early constitutional corpuscles [twenty-five]. For deterrent example, skating rink amide linker can buoy comprise made use of immediately because an alkylated diverseness scaffold to bring about N-alkylated amides au courant segmentation from the satisfying abide. Though the skating rink engineering science constitutes confined to the formulation of amides and carboxyl battery-acids, the public-service corporation of Rink-chloride canful appropriate the adhesion from respective nucleophiles with a all-embracing chain of mountains from operative groupings to the rosin, such as every bit aminoalkanes, inebriants and thiols [II].inwards addition, the know-how from skating rink resin trifluoroacetate dismiss constitute habituated to develop hydroxybenzenes [ternary] and purines.
Rink resin is originally developed for SPS of peptide amides. Now the scope of its application is extended from carboxylic amides to the immobilization of amines, substituted amides. Libaries of primary amines have been synthesized by the treatment of Rink amine resin with aldehyde to form aldimines, which are subsequently reacted with Grignard reagents or lithium reagents to yield amines that are not commercially available . These amines are released from resin by treatmnet with TFA-water-DCM (5:5:90) for 5 h at room temperature. N-Substituted amides are obtained by reducing the above-mentioned aldimines with Na(CN)BH3 to the corresponding amines, followed by acylation with acid chlorides or symmetrical anhydrides. The produts are cleaved with TFA-water-DCM (5:1:94) for 20 min at room temperature. Direct functionalization of Rink amide resin with nucleophiles has also been reported . The Fmoc protecting group can be readly removed with 20% piperidine in DMF prior to the above manipulation.

Friday, February 3, 2012

The Introduction of silver nanowires


silver nanowires
Silver nanowires is a nanometer scale (1 nm = 10 ^ -9 meters) line. Put another way, the nanowires can be defined as a limited to 100 nm in the horizontal (vertical limit) one-dimensional structure. This scale, quantum mechanical effects are important, also known as “quantum wire”. Depending on the constituent materials, the nanowires can be divided into different types, including metal nanowires (eg: Ni, Pt, Au), semiconductor nanowires (such as: of InP, Si, GaN, etc.) and the insulator nanowires (such as: SiO2, TiO2, etc.). Molecular nanowires by repeated molecular composition can be organic (such as: DNA) or inorganic (such as: Mo6S9-XIX). As an important part of nanotechnology, Silver nanowires can be used to make ultra-small circuit. Silver nanowires in addition to have excellent electrical conductivity of the silver, due to the size effect of nano-level, but also has excellent light transmittance, flexure resistance. Therefore be regarded as the most likely alternative to the traditional ITO transparent electrode material, to achieve flexible and can bend the LED display, touch screen, offers the possibility, and there are a lot of research to be used in thin film solar cells. In addition, the effect of the large aspect ratio of silver nanowires, it also has obvious advantages in the application of the conductive adhesive, thermal plastic.
Nano Silver line thin line thin film of transparent nano silver Transparent Silver Nanowire Films, a new transparent conductors: embedded in a transparent polymer A New the Transparent Conductor is: Silver Nanowire Film Buried at the the Surface of a the Transparent Polymer
Silver nanowires in addition to have excellent electrical conductivity of the silver, due to the size effect of nano-level, but also has excellent light transmittance, flexure resistance. Therefore be regarded as the most likely alternative to the traditional ITO transparent electrode material, to achieve flexible and can bend the LED display, touch screen, offers the possibility, and there are a lot of research to be used in thin film solar cells. In addition, the effect of the large aspect ratio of silver nanowires, it also has obvious advantages in the application of the conductive adhesive, thermal plastic.
Nanowires of metal nanoparticles has tremendous potential applications in catalysis, bio-detection, and the nature of the optical nature and shape of metal nanoparticles are closely related. Therefore, controlled synthesis of metal nanoparticles, including the adjustment of its morphology, size, causing more and more attention. In the synthesis process, the surfactant plays an important role in shape control of metal nanoparticles.




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Thursday, February 2, 2012

How to Buy Graphene nanosheets


 Graphene nanosheets
Graphene nanosheets has recently opened up an exciting new field in the science and technology of two-dimensional (2D) nanomaterials with continuously growing academic and technological impetus. GN exhibits unique electronic, optical, magnetic, thermal and mechanical properties arising from its strictly 2D structure and thus has many important technical applications. Actually, GN-based materials have enormous potential to rival or even surpass the performance of carbon nanotube-based counterparts, given that cheap, large-scale production and processing methods for high-quality GN become available. Therefore, the studies on GN in the aspects of chemistry, physical, materials, biology and interdisciplinary science have been in full flow in the past five years. In this critical review, from the viewpoint of chemistry and materials, we will cover recent significant advances in synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications of the "star-material" GN together with discussion on its major challenges and opportunities for future GN research ( 315 references).
Graphite film is composed of a single layer of carbon atoms tilting, then only one atom thick, with a high electrical conductivity. First made in 2004, only the adhesion of the other materials used. Now scientists have successfully used the framework of the gold nanorods system, it made a film. Recently, in the graphite film found a lot of surprising and interesting electronic transport phenomena.
The lithium storage properties of graphene nanosheet (GNS) materials as high capacity anode materials for rechargeable lithium secondary batteries (LIB) were investigated. Graphite is a practical anode material used for LIB, because of its capability for reversible lithium ion intercalation in the layered crystals , and the structural similarities of GNS to graphite may provide another type of intercalation anode compound. While the accommodation of lithium in these layered compounds is influenced by the layer spacing between the Graphene nanosheets, control of the intergraphene sheet distance through interacting molecules such as carbon nanotubes (CNT) or fullerenes (C60) might be crucial for enhancement of the storage capacity. The specific capacity of GNS was found to be 540 mAh / g, which is much larger than that of graphite, and this was increased up to 730 mAh / g and 784 mAh / g, respectively, by the incorporation of macromolecules of CNT and C60 to the GNS.
Graphite films in electronic devices has great prospect. U.S. scientists Watt, British researchers at the University of Manchester and the German Max Planck Institute researchers have produced a graphite film transistors. Graphite crystal silicon wafers with greater than the advantages. This transistor is not only very small, low cost, and for opening and closing of the voltage is very low, and therefore very sensitive to higher performance, faster, lower power consumption. Past attempts to create single-electron transistors are mostly using standard semiconductor materials, need to be cooled to near absolute zero in order to use, and graphite single-electron transistors can operate at room temperature work. And graphite transistor can be easily designed into the desired shapes. Therefore, be regarded as a substitute for the current chip transistors.


Wednesday, February 1, 2012

The Advantages of CMK-3


CMK-3
CMK-3 over the CAC, adsorption capacity, adsorption rate, and equilibrium time is short, is a good adsorbent, while of the mesoporous carbon CMK-3 for phenol adsorption thermodynamics and kinetics. CMK-3 adsorption of phenol used Langmuir and Freundlich isotherm to describe the correlation is good, but more in line with Freundlich empirical formula. were used to simulate first-order reaction and second-order reaction model examined the adsorption kinetics and the calculation of these dynamics model rate constants. analog second-order reaction model and experimental data a good correlation between the respectively calculated thermodynamic parameters ΔG0, ΔS0 and ΔH0, results show that, CMK-3 for phenol adsorption process is endothermic and spontaneous .
Mesoporous carbon is a new type of non-silicon-based mesoporous materials with large specific surface area (up to 2500m2 / g) and pore volume (up to 2.25cm3 / g), is expected to catalyst, hydrogen storage materials, electrode materials and other aspects of important applications, so are people’s attention. In addition, mesoporous materials obtained by the double-layer capacitance charge storage material above the metal oxide particles assembled electric capacity, far higher than commercially available metal oxide double-layer capacitors.
And pure mesoporous silica materials, mesoporous carbon materials exhibit unique properties, high specific surface area, high porosity; pore size adjustable within a certain range; mesoporous shapes, hole wall composition, structure and nature of the adjustable; by optimizing the synthesis conditions can be high thermal stability and hydrothermal stability; synthesis is simple, easy to operate, no physiological toxicity. It is still in its attraction of fuel cells, molecular sieve, adsorption, catalysis, electrochemistry and other areas of potential applications. In recent years, mesoporous materials science has become an international cross-chemistry, physics, materials, biology and other disciplines cross one of the hot areas of research, development of materials science have become an important milestone.
Mesoporous material as a photocatalyst for the treatment of environmental contaminants is one of the hot research in recent years. For example, mesoporous TiO2 Bi Nami TiO2 (P25) has a higher photocatalytic activity, because the mesoporous structure with high surface area to improve contact with organic molecules, an increase of surface adsorbed water and hydroxyl, water and hydroxyl groups with the catalyst surface can be excited by light the reaction of hydroxyl radical hole, and hydroxyl radical degradation of organic matter is a strong oxidant, can put a lot of biodegradable organic matter is oxidized to CO2 and water and other minerals. In addition, the ordered mesoporous materials for selective doping can improve the optical activity of visible light photocatalytic degradation of organic waste to increase the efficiency.
Now widely used in domestic water chlorine disinfection process though killed all bacteria, but had chloroform, carbon tetrachloride, monochloroacetic acid and a series of toxic organic compounds, its serious “three letter” effects (cancer, teratogenic, mutagenic) has attracted international scientific and medical community’s attention. Through the pores of mesoporous materials received on the inner wall of the school γ-chloropropyl triethoxysilane, has been functionalized mesoporous CPS-HMS, the functional mesoporous molecular sieves to remove traces of chloroform in water results are obvious, the removal rate of up to 97%. After the treated water chloroform concentrations below the national standard, even lower than the drinking water standards.



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