The information of (+)-Isopinocampheol

Synonym Name:
cis-pinocampheol; (1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol; bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1S,2S,3S,5R)-; (1S,2S,3S,5R)-2,6,6-Trimethyl-bicyclo[3.1.1]heptan-3-ol
The biotransformation of (+)-Isopinocampheol and (-) -isopinocampheol by Glomerella cingulata has been studied. Both substrates were adapted to three pinanediols, respectively. The above metabolic articles acquired were diols. The capital artefact of (−)-isopinocampheol was (1R, 2R, 3S, 4S, 5R)-3,4-pinanediol, and that of the (+)-enantiomer was (1S, 2S, 3S, 5R, 7R)-3,7-pinanediol. These after-effects accepted that the blaze by G. cingulata took abode with enantioselectivity. In addition, the aforementioned substrates were aswell adapted by added fungi such as Rhizoctonia solani and Aspergillus niger. Some similarities abide amid the capital articles of the metabolism of R. solani, while those of A. niger were somewhat different. © 1997 Elsevier Science Ltd.
A ferroelectric aqueous clear with an end-substituted (+)-Isopinocampheol accumulation has been advised in abreast and in mixtures with the antiferroelectric admixture EHPOCBC. The samples were advised with account to electroclinic coefficients, angle angles, X-ray band spacing, dielectric permittivity, ad-lib polarisation and about birefringence beneath an activated field. In the authentic isopinocampheol commissioned compound, the SmA∗-SmC∗phase alteration appears acerb aboriginal adjustment and is associated with a cogent access in able birefringence. The smectic band agreement decreases beneath the alteration about with the optical tilt. On added EHPOCBC absorption the change in birefringence beyond the alteration diminishes, until the point at which the admixture adopts an anticlinic SmC A ∗phase, and the accepted abatement in birefringence is observed.CAS NO.: 27779-29-9Molecular Formula: C10H18O
Molecular Weight: 154.25
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